|
Exactly what is carbon, and why does it play such an
important role in our economy and environment?
First of all, carbon is an integral part of almost
everything in our daily lives -- from propane to limestone rocks
to the steel in your car to dandelion plants to the nose on your
face and the air you breathe. Carbon exists in many forms. Among
other things, it forms the backbone of DNA, floats through the air
and water as carbon dioxide, and lays quietly for millions of
years as underground fossil fuels and limestone and dolomite rock
deposits.
Carbon is the sixth-most abundant element in the universe,
after hydrogen, helium, oxygen, neon, and nitrogen. It is the
product of the fusion of three helium nuclei.
In its elemental form, carbon (C) has an atomic number of 6
and an atomic weight of 12, which means it has 6 protons and 6
neutrons in its nucleus, surrounded by 6 electrons. Carbon cannot
lose or gain electrons to form free ions, but it can form strong
covalent bonds with many other elements. Carbon-hydrogen and
carbon-oxygen bonds are especially stable in nature.
Carbon is also unique among the elements in the almost
infinite capacity of its atoms to bond to each other in long
chains, or in rings. This is due to the strength of bonds between
carbon atoms. Carbon crystallizes in two forms, as diamonds and as
graphite. When long pure chains of carbon-carbon atoms form in
three dimensions, the result is the diamond. When pure carbon
chains form in two dimensions, the result is graphite, which can
be peeled apart easily in layers. Other long chains or rings of
carbon atoms exist in combination with hydrogen, oxygen, and
nitrogen atoms, and are called organic compounds.
In the gaseous state, carbon forms covalent bonds with
oxygen (carbon dioxide and carbon monoxide), hydrogen (methane),
and nitrogen (hydrogen cyanide), and other molecules. Carbon
dioxide levels in the atmosphere have increased by 30 percent
since the advent if the industrial revolution, from about 275
parts per million in the early 1700s to more than 365 parts per
million today. This level is estimated to increase to 450-600
parts per million by 2100. The primary cause of this increase is
increased combustion of fossil fuels. Deforestation and other
changes in vegetation management and land uses have also
contributed to the increase.
Carbon dioxide is also diffused within ocean waters. Once
dissolved in seawater, carbon dioxide can be converted into
carbonate or bicarbonate. Certain forms of sea life biologically
fix bicarbonate with calcium to produce calcium carbonate. This
substance is used to produce shells and other body parts by coral,
clams, oysters, and other organisms. When these organisms die, the
calcium carbonate materials sink to the ocean floor, where they
are eventually altered into sedimentary rocks. This is where most
of the carbon on earth exists.
Carbon dioxide is not a good oxidizing agent, and it does
not support the combustion of carbon-based substances. Rather, it
extinguishes the combustion of these substances and is often used
in fire extinguishers. Carbon monoxide, however, is combustible.
All organic compounds, such as proteins, carbohydrates, and
fats, contain carbon. All biological substances are based upon
compounds in which carbon is combined with other elements. All
plant and animal cells consist of carbon compounds and their
polymers.
Within the crust of the Earth, carbon exists in many
inorganic and organic forms. Carbonate minerals, calcium carbonate
and magnesium carbonate, are among the most abundant and widely
distributed minerals on the surface of the Earth. These minerals
take the form of limestone, dolomite, and marble, among others. In
terms of weight, however, oxygen and silicon together are about
2,500 times more prevalent in the Earth's surface rocks than
carbon. Coral and the shells of oysters and clams are primarily
calcium carbonate. In the organic form, carbon is widely
distributed in the lithosphere as coal, oil, natural gas, and all
plant and animal tissue.
What Is
Soil Organic Carbon?
Carbon also exists in the Earth's crust as soil organic
matter. Microorganisms in the soil convert decaying plant and
animal tissue into soil organic matter. Soil organic carbon often
is divided into three pools: active, intermediate or slow, and
recalcitrant.
The active pool typically stores carbon anywhere from a few
months to a few years. This pool typically accounts for less than
5 percent of the total soil carbon. The slow pool stores carbon
for decades, and accounts for 20 to 40 percent of total soil
carbon. The recalcitrant pool is extremely stable, and stores
carbon for hundreds or thousands of years before decomposing.
About 60 to 70 percent of total soil carbon is in the recalcitrant
pool.
|